Chemistry Letters p. 1821 - 1824 (1985)
Update date:2022-08-03
Topics:
Tada, Masaru
Inoue, Kunimi
Sugawara, Keiji
Hiratsuka, Mitsunori
Okabe, Masami
The possible involvement of cobalt in the radical reaarrangement of a thioester group was tested by using cobaloxime as a mimic of cobalamin.The coexistence of cobaloxime (II) species stimulates the rearrangement of the thioester group.A coordinative interaction between sulfur and cobalt is proposed for the assistance of this rearrangement.
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