REGIO AND STEREOSELECTIVE COUPLING REACTION OF GRIGNARD REAGENTS WITH β-PHENYLTHIO β,γ-UNSATURATED ALCOHOLS USING TETRACHLOROSILANE. A NEW METHOD FOR THE PREPARATION OF (Z)-ALKENYL SULFIDES

Article abstract of DOI:10.1246/cl.1985.1629

The coupling reaction of (E)-β-phenylthio β,γ-unsaturated alcohols with Grignard reagents using tetrachlorosilane as a condensation reagent gave (Z)-S_N2' products exclusively, whereas the reaction of the corresponding Z-isomers proceeded by S