ANION RADICAL-INDUCED DESILYLATION OF ORGANOSILANE. REACTIONS OF BENZYLSILANES WITH ALDEHYDES AND RELATED COMPOUNDS IN THE PRESENCE OF BUTYLLITHIUM OR LITHIUM METAL

DOI: 10.1246/cl.1985.1223

Source and publish data:

Chemistry Letters p. 1223 - 1226 (1985)

Update date:2022-07-30

Topics:

Authors:

Kanemasa, Shuji

Tanaka, Junji

Nagahama, Hideki

Tsuge, Otohiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1985.1223

By the action of butyllithium or lithium metal in such polar aprotic solvent as DMF or HMPA in the presence of aldehydes or related compounds, some benzylsilanes suffer from anion radicalinduced desilylation forming benzyl carbanions which add to the aldehydes and related compounds.

Full text of DOI:10.1246/cl.1985.1223

Products guided by the article

Product name:(E)-1-Methoxy-1,4-diphenyl-but-3-en-2-ol

Cas No:104367-62-6

R&D Labs maybe for 104367-62-6

Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Lanzhou SchiffChem Co.,Ltd

Contact:86-931-8272767

Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Shuanghe Bio-Technology Limited(expird)

Contact:+86-571-61710758,18968016640

Address:Jinqiao north road 916# Fuyang

Relevant to this article

Synthesis of pseudoiridolactones

Doi:10.1016/j.tet.2007.02.027
(2007)
Discovery of novel 17-phenylethylaminegeldanamycin derivatives as potent hsp90 inhibitors

Doi:10.1111/cbdd.12371
(2015)
Multisubstrate inhibitors of dopamine β-hydroxylase. 1. Some 1-phenyl and 1-phenyl-bridged derivatives of imidazole-2-thione

Doi:10.1021/jm00162a008
(1986)
Substituent Effects on Intramolecular Selectivity and Free Energy Relationships in Anodic and Metal Ion Oxidations of 5-X-1,2,3-trimethylbenzenes

Doi:10.1021/jo00374a010
(1986)
Ring transformation reactions of C-nucleosides: Facile synthesis of pyrazolo[1,5-a]pyrimidine and pyrazolo[1,5- a]triazine C-nucleosides

Doi:10.1002/jhet.5570230209
(1986)
Copper-catalyzed arylative meyer-schuster rearrangement of propargylic alcohols to complex enones using diaryliodonium salts

Doi:10.1002/anie.201301529
(2013)

Article Doi