ANION RADICAL-INDUCED DESILYLATION OF ORGANOSILANE. REACTIONS OF BENZYLSILANES WITH ALDEHYDES AND RELATED COMPOUNDS IN THE PRESENCE OF BUTYLLITHIUM OR LITHIUM METAL

DOI: 10.1246/cl.1985.1223

Source and publish data:

Chemistry Letters p. 1223 - 1226 (1985)

Update date:2022-07-30

Topics:

Authors:

Kanemasa, Shuji

Tanaka, Junji

Nagahama, Hideki

Tsuge, Otohiko

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Article abstract of DOI:10.1246/cl.1985.1223

By the action of butyllithium or lithium metal in such polar aprotic solvent as DMF or HMPA in the presence of aldehydes or related compounds, some benzylsilanes suffer from anion radicalinduced desilylation forming benzyl carbanions which add to the aldehydes and related compounds.

Full text of DOI:10.1246/cl.1985.1223

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