Inside-outside stereoisomerism. 5. Synthesis and reactivity of trans-bicyclo[n.3.1]alkanones prepared via the intramolecular photocycloaddition of dioxenones

DOI: 10.1021/ja00023a037

Source and publish data:

Journal of the American Chemical Society p. 8839 - 8846 (1991)

Update date:2022-08-04

Topics:

Authors:

Winkler, Jeffrey D.

Hong, Bor-Cherng

Hey, John P.

Williard, Paul G.

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Article abstract of DOI:10.1021/ja00023a037

The stereoselectivity of the intramolecular photocycloaddition of a series of bicyclic dioxenones has been examined. The selective formation of trans-fused photoadducts is observed in almost all cases, which upon fragmentation lead to the synthesis of bic

Full text of DOI:10.1021/ja00023a037

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