A New Method for Synthesis of Five-membered Carbocycles: Use of the Ester Enolate Rearrangement in Conjunction with Radical Cyclization

DOI: 10.1039/c39860000588

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 588 - 589 (1986)

Update date:2022-09-26

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Authors:

Mohammed, Ali Yousif

Clive, Derrick L. J.

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Article abstract of DOI:10.1039/c39860000588

4-(Phenylseleno)butyryl esters (2), easily prepared from allylic alcohols, are convertible into cyclopentanes by successive ester enolate rearrangement (2) -> (3) and 5-exo-trigonal radical cyclization (4) -> (6); this general process is efficient and the

Full text of DOI:10.1039/c39860000588

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