SYNTHESIS OF DL-PENTA-N,O-ACETYLVALIOLAMINE AND RELATED BRANCHED-CHAIN AMINOCYCLITOLS

DOI: 10.1016/S0008-6215(00)90393-8

Source and publish data:

Carbohydrate Research p. 257 - 264 (1986)

Update date:2022-07-31

Topics:

Authors:

Ogawa, Seiichiro

Shibata, Yasushi

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Article abstract of DOI:10.1016/S0008-6215(00)90393-8

Valiolamine (1), a branched-chin aminocyclitol α-D-glucosidase inhibitor, has been synthesized as the racemic penta-N,O-acetyl derivatives (10) from DL-(1,3/2,4)-1,2,3-triacetoxy-4-bromo-6-methylenecyclohxane (2).Epoxidation of 2 with m-chloroperbenzoic a

Full text of DOI:10.1016/S0008-6215(00)90393-8

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