STEREOSELECTIVE SYNTHESIS OF ALLYLSILANES FROM CHLOROMETHYLSILYLALKYNES

DOI: 10.1016/S0040-4039(00)84048-4

Source and publish data:

Tetrahedron Letters p. 589 - 592 (1986)

Update date:2022-08-02

Topics:

Authors:

Shiragami, Hiroshi

Kawamoto, Takuo

Utimoto, Kiitiro

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4039(00)84048-4

Regio- and stereoselective hydralumination of 1-chloromethyldimethylsilyl-1-alkyne with DIBAH affords (Z)-1-chloromethyldimethylsilyl-1-diisobutylalumino-1-alkene which gives (E)-1-trimethylsilyl-2-alkene as a sole product by successive treatment with 3 e

Full text of DOI:10.1016/S0040-4039(00)84048-4

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