SILVER TRIFLATE-PROMOTED COUPLING REACTIONS OF BENZYLIC AND ALLYLIC SULFIDES WITH O-SILYLATED ENOLATES OF KETONES AND ESTERS, A SYNTHESIS OF (+/-)-AR-TURMERONE

DOI: 10.1016/S0040-4039(00)94388-0

Source and publish data:

Tetrahedron Letters p. 265 - 266 (1990)

Update date:2022-07-29

Topics:

Authors:

Takeda, Kazuyoshi

Torii, Katsumi

Ogura, Haruo

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Article abstract of DOI:10.1016/S0040-4039(00)94388-0

Reactions of benzylic and allylic sulfides 1 having 5-mercapto-1-phenyl-1H-tetrazolyl group with O-silylated ketone and ester enolates 2 in the presence of silver triflate gave coupling products 3 in good yield. (+/-)-ar-turmerone was synthesized by this

Full text of DOI:10.1016/S0040-4039(00)94388-0

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