Journal of Organic Chemistry p. 4733 - 4734 (1986)
Update date:2022-07-30
Topics:
Liu, Chin
Wang, Kung K.
Allylborane 3, readily prepared from 1,2-bis-(trimethylsilyl)-2,3-butadiene by hydroboration with 9-borabicyclo<3.3.1>nonane, smoothly condenses with aldehydes and ketones to afford, after basic or acidic workup, a variety of 2-<(trimethylsilyl)methyl>-1,3-butadienes with the dienes derived from aldehydes having high isomeric purity.
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Doi:10.1039/c39860000915
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