Journal of Organic Chemistry p. 3744 - 3746 (1986)
Update date:2022-09-26
Topics:
Fife, Wilmer K.
Zhang, Zhi-dong
Two new mixed formic anhydrides, cinnamic formic anhydride and formic 4-methoxybenzoic anhydride, can be prepared in high yield ( c.a. 80percent) from equimolar mixtures of sodium formate and the appropriate acid chloride with a solid-phase copolymer of pyridine 1-oxide as catalyst, and they exhibit excellent selectivity as formylating agents of alcohols and amines
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