Tetrahedron Letters p. 6109 - 6112 (1985)
Update date:2022-09-26
Topics:
Tanaka, Masahide
Tomioka, Kiyoshi
Koga, Kenji
The first total synthesis of (+)-spatol (1) with natural configuration is described.The important step utilizes the carbon-carbon bond formation with simultaneous epoxide formation by the reaction of optically pure sulfonium ylide (4) and optically pure epoxy aldehyde (5).
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