MIXED (η2:η4)-COORDINATION OF para-SEMIQUINOID TRIENE LIGANDS (1-METHYLENE-4,4-DIALKYL-2,5-CYCLOHEXADIENES) WITH TWO TRANSITION METAL CENTRES IN BI- AND TRI-NUCLEAR RHODIUM(I) COMPLEXES

DOI: 10.1016/S0022-328X(00)98959-9

Source and publish data:

Journal of Organometallic Chemistry p. 351 - 362 (1986)

Update date:2022-08-03

Topics:

Authors:

Nikanorov, V. A.

Rozenberg, V. I.

Bakhmutov, V. I.

Reutov, O. A.

Ginzburg, B. I.

et al. et al.

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Article abstract of DOI:10.1016/S0022-328X(00)98959-9

The reaction between Rh(acac)(C2H4)2 and 1-methylene-4-methyl-4-R-2,5-cyclohexadienes (RC8H9) leads to binuclear complexes 2(C2H4)(RC8H9), where R = CH3, CHCl2 and n-C4H9, in which triene ligands show a mixed (η²:η⁴) mode o

Full text of DOI:10.1016/S0022-328X(00)98959-9

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