A Divergent Route for a Total Synthesis of Cyclophellitol and Epicyclophellitol from a Oxabicyclic Glycoside Prepared from D-Glucal

DOI: 10.1021/jo00091a004

Source and publish data:

Journal of Organic Chemistry p. 3250 - 3252 (1994)

Update date:2022-08-03

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Authors:

McDevitt, R. E.

Fraser-Reid, B.

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Article abstract of DOI:10.1021/jo00091a004

D-Glucal has been used for syntheses of Tatsuta's penultimate intermediate for cyclophellitol and epicyclophellitol via a 6-exo-trig radical cyclization of 2-deoxy-2-iodo-6-alkynyl glycoside, the diastereomeric mixture produced thereby being separated into two sets, each of which leads to one or other target materials.

Full text of DOI:10.1021/jo00091a004

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