Journal of Organic Chemistry p. 3250 - 3252 (1994)
Update date:2022-08-03
Topics:
McDevitt, R. E.
Fraser-Reid, B.
D-Glucal has been used for syntheses of Tatsuta's penultimate intermediate for cyclophellitol and epicyclophellitol via a 6-exo-trig radical cyclization of 2-deoxy-2-iodo-6-alkynyl glycoside, the diastereomeric mixture produced thereby being separated into two sets, each of which leads to one or other target materials.
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