REACTION OF (E)-PHENYL 2-PYRIDYL KETONE O-ACYLOXIMES (PPAO) WITH GRIGNARD REAGENTS. A CONVENIENT AND HIGHLY CHEMOSELECTIVE SYNTHESIS OF KETONES

DOI: 10.1246/cl.1986.449

Source and publish data:

Chemistry Letters p. 449 - 452 (1986)

Update date:2022-08-03

Topics:

Authors:

Miyasaka, Tadayo

Monobe, Hideaki

Noguchi, Shunsaku

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1986.449

The reaction of (E)-phenyl 2-pyridyl ketone O-acyloximes (PPAO) with Grignard reagents was found to be widely applicable to the chemoselective synthesis of various ketones in good yields under mild conditions.

Full text of DOI:10.1246/cl.1986.449

Products guided by the article

Product name:3-Heptanone, 7-bromo-1-phenyl-

Cas No:105769-54-8

R&D Labs maybe for 105769-54-8

Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd

Contact:+86-517-86283327

Address:9 North Hantai Road, Huaian, China

Relevant to this article

Asymmetric synthesis of jaspine B (pachastrissamine) via an organocatalytic Aldol reaction as key step

Doi:10.1055/s-2008-1067142
(2008)
[1-(Phenylthio)-2-carbamoylallyl]lithium reagents. Electrophilic substitution and formal anionic 3 + 2 cyclization-elimination

Doi:10.1021/jo00378a011
(1987)
Vitamin D relatives. Part I. B-thiophene-des-A-cholestanes. Solvolytic reactions of some derivatives of 2,2-disubstituted cyclohexane-1,4-diol and 4-hydroxycyclohexan-1-one

Doi:10.1139/v86-252
(1986)
Nickel phosphide nanocatalysts for the chemoselective hydrogenation of alkynes

Doi:10.1016/j.nantod.2011.12.003
(2012)
The Mannich reaction in the synthesis of N,S-containing heterocycles 6. New approaches to the synthesis of pyrimido[4,3-b][1,3,5]thiadiazine derivatives

Doi:10.1007/s11172-007-0226-6
(2007)
Studies on cardiac ingredients of plants. XI. synthesis of new bufotoxin homologues utilizing scillarenin (the genuine aglycone of proscillaridin), and their biological activities

Doi:10.1248/cpb.42.2256
(1994)

Article Doi