Bulletin of the Chemical Society of Japan p. 1429 - 1432 (1987)
Update date:2022-08-05
Topics:
Takeshita, Hitoshi
Mori, Akira
Suizu, Hiroshi
The base-catalyzed rearrangement of 2-(2-nitro-, 4-nitro-, and 4-cyanobenzyloxy)tropones smoothly yielded corresponding 2-<(aryl)hydroxymethyl>tropones, while their thermolysis gave 3-(arylmethyl)tropolones.This reaction has no precedent analogy in tropon
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