Journal of Organic Chemistry p. 961 - 967 (1985)
Update date:2022-08-04
Topics:
Andriamialisoa, Ratremaniaina Zo
Langlois, Nicole
Langlois, Yves
Highly stereoselective total syntheses of indole alkaloids vindorosine (1a) and vindoline (1b) are described.An imino Diels-Alder reaction, a stereospecific alkylation, and a rearrangement induced by the Pummerer reaction are the key steps of these short and high overall yield sequences.
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Doi:10.1021/jo049132r
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