A New Efficient Total Synthesis of Vindorosine and Vindoline

DOI: 10.1021/jo00207a011

Source and publish data:

Journal of Organic Chemistry p. 961 - 967 (1985)

Update date:2022-08-04

Topics:

Authors:

Andriamialisoa, Ratremaniaina Zo

Langlois, Nicole

Langlois, Yves

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Article abstract of DOI:10.1021/jo00207a011

Highly stereoselective total syntheses of indole alkaloids vindorosine (1a) and vindoline (1b) are described.An imino Diels-Alder reaction, a stereospecific alkylation, and a rearrangement induced by the Pummerer reaction are the key steps of these short and high overall yield sequences.

Full text of DOI:10.1021/jo00207a011

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