Journal of the Chemical Society. Chemical communications p. 1248 - 1250 (1986)
Update date:2022-07-30
Topics:
Voegtle, Fritz
Struck, Johannes
Puff, Heinrich
Woller, Petra
Reuter, Hans
The helical structures of the new highly strained <2,2>-metacyclophanes (5) (the structure of which has been determined by X-ray crystallography) and (8) have been studied and the four stereoisomeric sulphoxides (6) obtained from (5) have been separated by h.p.l.c.; the diastereomeric excess in the oxidation of the helical sulphide (5) to yield the sulphoxides (6) is 91 percent.
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Doi:10.1246/bcsj.59.1767
(1986)Doi:10.1016/S0040-4039(01)86706-X
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