Tetrahedron Letters p. 2649 - 2652 (1986)
Update date:2022-09-26
Topics:
Nishinaga, Akira
Yamazaki, Shigekazu
Matsuura, Teruo
Oxygenation of aromatic ketone hydrazones with Co(salen) in methanol resulted unexpectedly in oxidative degradation to give methyl benzoate derivatives.A mechanism involving nucleophilic attack by methanol on a diazo intermediate is discussed.
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