
Chemistry Letters p. 1385 - 1388 (1986)
Update date:2022-08-04
Topics:
Mukaiyama, Teruaki
Miyoshi, Norikazu
Kato, Jun-ichi
Ohshima, Masahiro
In the presence of a catalytic amount of trityl perchlorate, aldehydes smoothly react with t-butyl trimethylsilyl peroxide to give the acetal-type diperoxides in good yields.Treatment of these diperoxides with piperidine at 90 degC or the aqueous solution of CuSO4 and L-ascorbic acid at room temperature gave the corresponding carboxylic acids in good yields.
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