Journal of Organic Chemistry p. 1803 - 1810 (1987)
Update date:2022-09-26
Topics: Synthesis Polyenes Cyclization Anticancer
Kato, Tadahiro
Aoki, Mario
Uyehara, Tadao
On the basis of retrosynthetic perspective (Scheme I), the asperdiol skeleton (I = 24) and its geometrical isomer (II = 25) were constructed from cis- and trans-isopropenyl alcohols 3a and 3b.I(24) was converted into (+/-)-asperdiol 1 by the sequential re
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