Tetrahedron p. 315 - 328 (1986)
Update date:2022-08-03
Topics:
Flamming, R.
Lacombe, S.
Laurent, A.
Maquestiau, A.
Marquet, B.
Novkova, S.
Reactivity of protonated azirines is studied in solution and by chemical ionization in the gazeous phase.Azirinium ion produces an α-iminocarbenium ; its reactivity is studied.Mass spectrometry (CID- MIKE technic) proves the rearrangement of the α-iminocarbenium in a nitrilium ion.This nitrilium can also be obtained in solution.
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