DESIGN OF LIGANDS DERIVED FROM SULFUR CONTAINING AMINO ACIDS FOR ENANTIOSELECTIVE CROSS COUPLING CATALYZED BY NICKEL. INTRAMOLECULAR PARTICIPATION OF SULFIDE

DOI: 10.1016/S0040-4039(00)84446-9

Source and publish data:

Tetrahedron Letters p. 2049 - 2052 (1986)

Update date:2022-07-30

Topics:

Authors:

Vriesema, Bindert K.

Kellogg, Richard M.

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Article abstract of DOI:10.1016/S0040-4039(00)84446-9

A rationally designed ligand, 2-dimethylamino-1-diphenylphosphino-5-methylthiopentane (homomethphos) shows high efficiency in the nickel catalyzed cross coupling of the Grignard reagent from 1-chloro-1-phenylethane with vinyl bromide.

Full text of DOI:10.1016/S0040-4039(00)84446-9

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