DILITHIUM TETRACHLOROCUPRATE. A REAGENT FOR REGIOSELECTIVE CLEAVAGE OF EPOXIDE TO CHLOROHYDRINS.

DOI: 10.1016/S0040-4039(00)83856-3

Source and publish data:

Tetrahedron Letters p. 3697 - 3700 (1986)

Update date:2022-08-05

Topics:

Authors:

Ciaccio, James A.

Addess, Kenneth J.

Bell, Thomas W.

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Article abstract of DOI:10.1016/S0040-4039(00)83856-3

The title compound reacts with epoxides to selectively afford the vicinal chlorohydrin resulting from attack by chloride at the less substituted carbon atom.

Full text of DOI:10.1016/S0040-4039(00)83856-3

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