ALLYLPLATINUM AND PLATINUM(0) COMPLEXES WITH PHOSPHORUS-SULFUR MIXED LIGANDS

DOI: 10.1016/S0022-328X(00)99692-X

Source and publish data:

Journal of Organometallic Chemistry p. 267 - 270 (1986)

Update date:2022-08-03

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Authors:

Bressan, Mario

Morvillo, Antonino

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Article abstract of DOI:10.1016/S0022-328X(00)99692-X

Monomeric η¹-allyl complexes , (PSR = Ph2P(CH2)2SR, R = Me, Ph) are rapidly converted in polar media into the η³-allyl derivatives BF4.The NMR characteristics of both types of complex are discussed.

Full text of DOI:10.1016/S0022-328X(00)99692-X

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Product name:[Pt(C₃H₅)((C₆H₅)2P(CH₂)2SC₆H₅)]⁽¹⁺⁾*BF₄^(1-)=[Pt(C₃H₅)((C₆H₅)2P(CH₂)2SC₆H₅)]BF₄

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