A Simple Procedure for the Preparation of Chiral 'Tris(hydroxymethyl)methane' Derivatives

DOI: 10.1002/hlca.19930760130

Source and publish data:

Helvetica Chimica Acta p. 459 - 475 (1993)

Update date:2022-08-03

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Authors:

Seebach, Dieter

Lapierre, Jean-Marc

Jaworek, Wilfried

Seiler, Paul

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Article abstract of DOI:10.1002/hlca.19930760130

The aldol adducts 1a-13a of (R,R)-2-(tert-butyl)-6-methyl-1,3-dioxan-4-one (from 3-hydroxybutanoic acid) to aldehydes, single diastereoisomers obtained as described previously, are acetylated or benzoylated to the corresponding esters 1b-5b and 6c-13c, re

Full text of DOI:10.1002/hlca.19930760130

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Product name:(1'RS,2R,5R,6R)-2-(tert-butyl)-5-(α-hydroxybenzyl)-6-methyl-1,3-dioxan-4-one

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