
Journal of Organic Chemistry p. 595 - 598 (1990)
Update date:2022-08-03
Topics: Starting Material Reaction Conditions Purification and Isolation Nucleophilic Attack Reaction Mechanism Tautomerization Base Catalyst
Tamura, Rui
Kusama, Yukihiro
Oda, Daihei
A methodology for the selective base-catalyzed isomerization of certain epoxides having a β-proton into ketones is presented. β,γ-Epoxy nitro compounds were the substrates for this transformation and underwent a multistep reaction consisting of epoxide ri
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