HIGHLY DIASTEREOSELECTIVE SYNTHESIS OF 1,2-EPOXY-4-HYDROXYALKYL CARBAMATES. MASKED AND ACTIVATED α,γ-DIHYDROXY-ALKANALS AND -ALKANONES

DOI: 10.1016/S0040-4039(00)84857-1

Source and publish data:

Tetrahedron Letters p. 3591 - 3594 (1986)

Update date:2022-07-29

Topics:

Authors:

Hoppe, Dieter

Luessmann, Joerg

Jones, Peter G.

Schmidt, Dieter

Sheldrick, George M.

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Article abstract of DOI:10.1016/S0040-4039(00)84857-1

(Z)-anti-4-hydroxy-1-alkenylcarbamates 1 yield with essentially complete diastereoselectivity, the epoxides 2 with (1Z)-2,3-anti-3,4-anti-configuration on treatment with tert.-butylhydroperoxide/vanadylbis(acetoacetonate).

Full text of DOI:10.1016/S0040-4039(00)84857-1

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