ENANTIOSELECTIVE SYNTHESES OF (+)-α-SKYTANTHINE, (+)-δ-SKYTANTHINE AND (+)-IRIDOMYRMECIN BY AN INTRAMOLECULAR MAGNESIUM-ENE REACTION.

DOI: 10.1016/S0040-4039(00)84199-4

Source and publish data:

Tetrahedron Letters p. 1141 - 1144 (1986)

Update date:2022-09-26

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Authors:

Oppolzer, Wolfgang

Jacobsen, E. Jon

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Article abstract of DOI:10.1016/S0040-4039(00)84199-4

Starting from (S)-3-methyl-1-penten-5-ol 3a enantiomerically pure (+)-α-skytanthine 9, (+)-δ-skytanthine 11 and (+)-iridomyrmecin 12 were synthesized via the magnesium-ene rection 2*1.

Full text of DOI:10.1016/S0040-4039(00)84199-4

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