Helvetica Chimica Acta p. 2026 - 2037 (1986)
Update date:2022-08-03
Topics:
Maurer, Bruno
Hauser, Arnold
Ohloff, Guenther
Six sesquiterpenoids 1-6, formally derived from (+)-(S)-nerolidol by oxidative cyclization, have been isolated for the first time from commerical cabreuva oil.Whereas the two tetrahydrofurans 5 and 6 have already been described, the four bicyclic ethers (cabreuva oxides A-D) 1-4 are new.The structures of 1-4 are confirmed by synthesis and their absolute configurations are shown to be 3S.The organoleptic properties of the synthetic cabreuva oxides are discussed.
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(1987)
