- and -Cycloadditions of the Cyclohepta-2,4-dienyl Cation

DOI: 10.1021/jo00386a017

Source and publish data:

Journal of Organic Chemistry p. 1989 - 1993 (1987)

Update date:2022-07-29

Topics:

Authors:

Heilmann, Werner

Koschinsky, Rainer

Mayr, Herbert

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Article abstract of DOI:10.1021/jo00386a017

The cyclohepta-2,4-dienyl cation (9), generated in situ from 5-chloro-1,3-cycloheptadiene (10) and zinc chloride, undergoes a <3 + 2>-cycloaddition with 1-phenylpropyne (11) to give the bicyclo<4.2.1>nona-2,7-dien-9-yl cation (18), which is stereoselectiv

Full text of DOI:10.1021/jo00386a017

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