Journal of the American Chemical Society p. 2812 - 2817 (1987)
Update date:2022-09-26
Topics:
Chen, Ching-Shih
Wu, Shih-Hsiung
Girdaukas, Gary
Sih, Charles J.
New quantitative expressions, which relate the kinetic and thermodynamic parameters that govern the stereospecificity of enzyme-catalyzed resolution of enantiomers in biphasic aqueous-organic media, have been developed.The theoretical predictions have been verified experimentally, and the technical merit of this esterification methodology has been assessed in relation to the more conventional hydrolytic procedure.
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Doi:10.1248/cpb.35.229
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