Tetrahedron p. 6473 - 6484 (1997)
Update date:2022-07-30
Topics: Enantiomerically pure Experimental
Koskinen, Ari M. P.
Otsomaa, Leena A.
New efficient synthetic routes have been developed starting from the fully protected L-threonine derivative 1 for some deoxy-4-aminohexoses: methyl 4-amino-4,6-dideoxy gulopyranoside 2 and epi-tolyposamine 3. The title compounds were synthesized using an improved Horner-Emmons reaction of the threonine derived aldehyde 7. A new method for selective removal of the aminal protection is also reported.
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Doi:10.1021/ja01259a005
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