INTRAMOLECULAR RADICAL CYCLIZATION OF PHENOLIC NITRONATES: FACILE SYNTHESIS OF ANNELATED TROPONE AND TROPOLONE DERIVATIVES

DOI: 10.1016/S0040-4039(00)85396-4

Source and publish data:

Tetrahedron Letters p. 6051 - 6054 (1986)

Update date:2022-07-29

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Authors:

Kende, Andrew S.

Koch, Kevin

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Article abstract of DOI:10.1016/S0040-4039(00)85396-4

Treatment of the phenolic nitroalkanes 1 in dilute base with K3Fe(CN)6 results in the formation of spirocyclic nitro dienones 3 which undergo facile rearrangement to annelated tropone or tropolone derivatives.

Full text of DOI:10.1016/S0040-4039(00)85396-4

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