Synthesis of Cycloalkanones by Olefin Cyclization Initiated by Pummerer Reaction Products

DOI: 10.1055/s-1986-31801

Source and publish data:

Synthesis p. 847 - 849 (1986)

Update date:2022-07-30

Topics:

Authors:

Ishibashi, Hiroyuki

Harada, Suzumi

Okada, Motofumi

Ikeda, Masazumi

Ishiyama, Ko-ichi

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1986-31801

On treatment with trifluoroacetic anhydride, 1-methylsulfinyl-5-hepten-2-one undergoes cyclization via its Pummerer reaction product to give 3-ethenyl-2-(methylthio)cyclopentanone.This scope of the reaction for synthesis of cyclohexanone and cycloheptanone derivatives was explored.

Full text of DOI:10.1055/s-1986-31801

Products guided by the article

Product name:Trifluoro-acetic acid 1-methyl-3-methylsulfanyl-4-oxo-cyclohexyl ester

Cas No:108264-51-3

R&D Labs maybe for 108264-51-3

Jintan Jinnuo Chemical Co., Ltd.

Contact:+86-519-80199901

Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China
Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
Taizhou Crene Biotechnology co.ltd

Contact:86-576-88813233 88205808

Address:Economic Developed Zone of Taizhou Zhejiang China
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Suzhou Time-chem Technologies Co., Ltd.

Contact:0512-63983931/68086856

Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China

Relevant to this article

An improved synthesis of 1-acetyl-1H-indol-3-yl acetates

Doi:10.1002/jhet.5570440146
(2007)
Does neighboring group participation by non-vicinal esters play a role in glycosylation reactions? Effective probes for the detection of bridging intermediates

Doi:10.1021/jo801630m
(2008)
High-valent Paramagnetic Ruthenium(IV) Complexes Containing Multianionic Chelating Ligands as Efficient Catalysts for Alkene Epoxidation; X-Ray Crystal Structure of 2IV(chbae)(PPh3)(py)>*Et2O*2H2O

Doi:10.1039/c39870000418
(1987)
Monoanionic {Mn(NO)}⁵ and dianionic {Mn(NO)}⁶ thiolatonitrosylmanganese complexes: [(NO)Mn(L)₂]^- and [(NO)Mn(L)₂]^2- (LH₂ = 1,2-Benzenedithiol and toluene-3,4-dithiol)

Doi:10.1021/ic801553s
(2008)
Selenium containing heterocycles: Part 1. Synthesis of some new substituted pyrido[3',2':4,5]selenolo[3,2-d]pyrimidines and related fused tetracyclic systems

Doi:10.3184/030823407X25506
(2007)
All-polymer photovoltaic devices of poly(3-(4-n-octyl)-phenylthiophene) from grignard metathesis (GRIM) polymerization

Doi:10.1021/ja9059359
(2009)

Article Doi