Syn Bromination of 2-Cyclohexen-1-ol Benzoates. Isolation of a trans-3-Bromocyclohexano-cis-1,2-(2'-anisyl-1',3'-dioxolan-2'-ylium) Intermediate

DOI: 10.1021/jo00391a034

Source and publish data:

Journal of Organic Chemistry p. 3355 - 3362 (1987)

Update date:2022-08-04

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Authors:

Bellucci, Giuseppe

Bianchini, Roberto

Vecchiani, Sandra

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Article abstract of DOI:10.1021/jo00391a034

The addition of molecular bromine to 2-cyclohexen-1-ol benzoate, p-methylbenzoate, and p-methoxybenzoate in aprotic solvents of low to moderate dielectric constant gave, besides the expected vicinal trans diaxial and diequatorial dibromides, large amounts

Full text of DOI:10.1021/jo00391a034

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