COMPETITION BETWEEN VINYLIC SUBSTITUTION AND CONJUGATE ADDITION IN THE REACTIONS OF VINYL SELENOXIDES AND VINYL SELENONES WITH NUCLEOPHILES IN DMF

DOI: 10.1016/S0040-4020(01)82071-8

Source and publish data:

Tetrahedron p. 4889 - 4896 (1986)

Update date:2022-07-29

Topics:

Authors:

Tiecco, Marcello

Chianelli, Donatella

Testaferri, Lorenzo

Tingoli, Marco

Bartoli, Donatella

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Article abstract of DOI:10.1016/S0040-4020(01)82071-8

Vinyl selenoxides and vinyl selenones present a different reactivity towards thiolate or alkoxide anions in DMF.In the case of selenoxides the addition of the nucleophiles regioselectively occurs at the α-carbon leading to the formation of the vinylic sub

Full text of DOI:10.1016/S0040-4020(01)82071-8

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