GENERATION OF THIOCARBONYL YLIDES WITH RELEASE OF DISILOXANE FROM BIS(TRIMETHYLSILYLMETHYL) SULFOXIDES

DOI: 10.1016/S0040-4039(00)84905-9

Source and publish data:

Tetrahedron Letters p. 4039 - 4042 (1986)

Update date:2022-07-29

Topics:

Authors:

Aono, Masahiro

Hyodo, Chiaki

Terao, Yoshiyasu

Achiwa, Kazuo

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Article abstract of DOI:10.1016/S0040-4039(00)84905-9

A novel and general method for generation of thiocarbonyl ylide by release of disiloxane from bis(trimethylsilylmethyl) sulfoxide (1) has been found.This method was also demonstrated for generation of aliphatic and aromatic thioaldehyde S-methylide.

Full text of DOI:10.1016/S0040-4039(00)84905-9

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