Tetrahedron Letters p. 2845 - 2848 (1986)
Update date:2022-08-05
Topics:
Kaczmarek, Reinhard
Blechert, Siegfried
The de Mayo sequence has been applied to an efficient synthesis of the enone 6, a key intermediate in the synthesis of taxane derivatives.The palladium-catalyzed reaction of the allyl carbonates 9 and 11 gives via retro-aldol reaction and allylation the highly functionalized seven- resp. eightmembered rings 10 and 12.
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Doi:10.1016/S0040-4039(00)84907-2
(1986)Doi:10.1021/ja01537a037
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(2008)Doi:10.1002/ejoc.200800512
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(2018)Doi:10.1021/ol801294b
(2008)
