
Tetrahedron p. 4875 - 4886 (1987)
Update date:2022-08-05
Topics:
Solaja, Bogdan
Huguet, Joan
Karpf, Martin
Dreiding, Andre S.
The first synthesis of racemic isoptychanolide (2), a stereoisomer of natural ptychanolide (1), which differs in the configuration of the oxirane function, is reported.The key steps were an α-alkinone cyclisation (5 <*> 4, gas phase flow thermolysis at 62
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Doi:10.1016/j.ejmech.2007.12.009
(2008)Doi:10.1002/ejoc.200800687
(2008)Doi:10.1002/chem.201203254
(2013)Doi:10.1021/jo00392a031
(1987)Doi:10.1021/ja00092a010
(1994)Doi:10.1021/jo00392a035
(1987)