CAGE KETONES FROM DIMETHYL-1,4-BENZOQUINONES AND QUINONOID CARBANIONS; A CHARGE-TRANSFER CONTROLLED SYNTHESIS

DOI: 10.1016/S0040-4020(01)87334-8

Source and publish data:

Tetrahedron p. 3663 - 3676 (1986)

Update date:2022-07-31

Topics:

Authors:

Dean, Francis M.

Houghton, Leonard E.

Mitchell, Gordon H.

Nayyir-Mashir, Rassoul

Thebtaranonth, Chachanat

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Article abstract of DOI:10.1016/S0040-4020(01)87334-8

3-Methyl-1,4-naphthoquinon-2-ylmethyl anion (1a) adds 2,6-dimethyl-1,4-benzoquinone reversibly giving, in addition to products of types already known, a derivative (2) of the cage hydrocarbon decahydro-4,1,7-ethanylidenenaphthalene which can be obtained a

Full text of DOI:10.1016/S0040-4020(01)87334-8

Products guided by the article

Product name:3,4,4a,6,7,8a-hexahydro-4,7,8a,9-tetramethyl-6-(3-methyl-1,4-naphthoquinon-2-ylmethyl)-4,1,7-ethanylylidenenaphthalene-2(1H)-5,8,10-tetraone

Cas No:108646-83-9

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