Tetrahedron Letters p. 3307 - 3310 (1986)
Update date:2022-07-31
Topics: Diastereoselectivity NMR spectroscopy Ligand Stereochemistry Enantioselectivity Steric hindrance Stereocontrol Mechanistic Studies Electronic effects Reaction Kinetics Chiral Catalyst Solvent Effects Catalyst Loading HPLC Analysis Substrate Control Temperature Effects Turnover frequency (TOF)
Brown, John M.
Cutting, Ian
Evans, Phillip L.
Maddox, Peter J.
The degree of asymmetric induction observed in hydrogenation of menthyl 3-hydroxy-2-methylenebutyrates catalysed by DIPAMP-Rh+ complexes is strongly dependent on anti-reduction product is formed with high enantioselection.
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