Single-Electron-Transfer Pathway in the Coupling of Cyclopropenyl Cations with Organometallic Reagents

DOI: 10.1021/jo00391a018

Source and publish data:

Journal of Organic Chemistry p. 3278 - 3285 (1987)

Update date:2022-07-29

Topics:

Authors:

Padwa, Albert

Goldstein, Steven I.

Rosenthal, Robert J.

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Article abstract of DOI:10.1021/jo00391a018

Treatment of diphenylmethylcyclopropenylium perchlorate with various Grignard reagents produced substituted cyclopropenes in excellent yield.Alkyl and vinylic Grignard reagents react at the methylated carbon atom.The substantial increase in formation of t

Full text of DOI:10.1021/jo00391a018

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