Synthesis of the Parent 1,7-Cyclohexenonorbornadiene and Its Quadricyclane Valence Tautomer

DOI: 10.1021/jo00391a014

Source and publish data:

Journal of Organic Chemistry p. 3250 - 3253 (1987)

Update date:2022-07-31

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Authors:

Paquette, Leo A.

Racherla, Uday S.

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Article abstract of DOI:10.1021/jo00391a014

Cyclopentadiene is transformed in five steps into 1,7-cyclohexenonorbornadiene (10).Sensitized irradiation of this triene led to quadricyclane formation (11).The 1H and 13C NMR spectra of these hydrocarbons are compared to each other and to those of simpl

Full text of DOI:10.1021/jo00391a014

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