Bulletin of the Chemical Society of Japan p. 2865 - 2868 (1986)
Update date:2022-09-26
Topics:
Suga, Takayuki
Hirata, Toshifumi
Hamada, Hiroki
The stereochemistry in the reduction of the C-C double bond adjacent to the carbonyl group with the cultured cells of Nicotiana tabacum was investigated by feeding (4R)-<6-2H>-(-)-carvone to the cultured cells.It was found that the hydrogen attack to the C-C double bond takes place stereospecifically from the si-face at C-1 and the re-face at C-6, being trans-addition.
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