The Stereochemistry of the Reduction of Carbon-Carbon Double Bond with the Cultured Cells of Nicotiana tabacum

DOI: 10.1246/bcsj.59.2865

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2865 - 2868 (1986)

Update date:2022-09-26

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Authors:

Suga, Takayuki

Hirata, Toshifumi

Hamada, Hiroki

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Article abstract of DOI:10.1246/bcsj.59.2865

The stereochemistry in the reduction of the C-C double bond adjacent to the carbonyl group with the cultured cells of Nicotiana tabacum was investigated by feeding (4R)-<6-2H>-(-)-carvone to the cultured cells.It was found that the hydrogen attack to the C-C double bond takes place stereospecifically from the si-face at C-1 and the re-face at C-6, being trans-addition.

Full text of DOI:10.1246/bcsj.59.2865

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