Tetrahedron p. 4563 - 4576 (1986)
Update date:2022-08-03
Topics:
Pascual Teresa, J. de
Urones, J. G.
Montana Pedrero, A.
Basabe Barcala, P.
The reactivity of the methyl labdanolate, 3 with Pb(OAc)4 and/or Pb(OAc)4/I2 was studied.The long distance functionalization at C-12 led to compounds 8b and 9b, whose oxidation with RuO4 produced 16 at a 100percent yield.Compounds 14 and 15 were obtained
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