Tetrahedron Letters p. 2833 - 2836 (1990)
Update date:2022-08-03
Topics:
Liu, Wei Guo
Rosazza, John P. N.
The new bacterial catalyst, Bacillus cereus hydroxylates 1,8-cineole (1) to give 6R-exo-hydroxy-1,8-cineole, <(1R,4s,6R)-1,3,3-trimethyl-2-oxabicyclo(2,2,2)-octane-6-ol>, (3).The regio- and stereochemical outcome of this reaction was predicted using a model for the B. cereus hydroxylase.
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