STEROEPECIFIC HYDROXYLATION OF 1,8-CINEOLE USING A MICROBIAL BIOCATALYST

DOI: 10.1016/0040-4039(90)80160-N

Source and publish data:

Tetrahedron Letters p. 2833 - 2836 (1990)

Update date:2022-08-03

Topics:

Authors:

Liu, Wei Guo

Rosazza, John P. N.

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Article abstract of DOI:10.1016/0040-4039(90)80160-N

The new bacterial catalyst, Bacillus cereus hydroxylates 1,8-cineole (1) to give 6R-exo-hydroxy-1,8-cineole, <(1R,4s,6R)-1,3,3-trimethyl-2-oxabicyclo(2,2,2)-octane-6-ol>, (3).The regio- and stereochemical outcome of this reaction was predicted using a model for the B. cereus hydroxylase.

Full text of DOI:10.1016/0040-4039(90)80160-N

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