Asymmetric and 'anti'-Selective Aldolisations of Acetates and Propionates

DOI: 10.1002/hlca.19860690725

Source and publish data:

Helvetica Chimica Acta p. 1699 - 1703 (1986)

Update date:2022-08-04

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Authors:

Oppolzer, Wolfgang

Marco-Contelles, Jose

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Article abstract of DOI:10.1002/hlca.19860690725

Starting from acetates 1 and propionates 6, TiCl4-mediated addition of their silylketene acetals 2 and 7 to aldehydes gave aldols 4 and 9, respectively, with high ?-face and 'anti' differentiation (Schemes, and Tables 1 and 2).Alternation of the (E/Z)-eno

Full text of DOI:10.1002/hlca.19860690725

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