1,3-Dipoles Are Not the Only Reactive Species in 2-Acylaziridine Pyrolyses

DOI: 10.1021/jo00391a072

Source and publish data:

Journal of Organic Chemistry p. 3487 - 3488 (1987)

Update date:2022-07-29

Topics:

Authors:

Vedejs, E.

Wisniewski Grissom, J.

Preston, J. K.

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Article abstract of DOI:10.1021/jo00391a072

Pyrolysis of N-tert-butylaziridines 1 in the presence of acetylenedicarboxylate gives adducts of structure 5, which rearrange to 6, rather than the expected ylide adducts 4.

Full text of DOI:10.1021/jo00391a072

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