Asymmetric Allylic Alkylation of 1,3-Disubstituted 2-Propenyl Acetetes Catalyzed by a Chiral Ferrocenylphosphine-Palladium Complex

DOI: 10.1246/cl.1987.177

Source and publish data:

Chemistry Letters p. 177 - 180 (1987)

Update date:2022-07-30

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Authors:

Hayashi, Tamio

Yamamoto, Akihiro

Ito, Yoshihiko

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Article abstract of DOI:10.1246/cl.1987.177

Reaction of racemic 2-propenyl acetates substituted with two different aryl groups at 1 and 3 positions with sodium acetylacetonate in the presence of a palladium catalyst containing an optically active ferrophosphine ligand gave regioisomeric allylic alkylation products of high optical purity (up to 95 percent ee).

Full text of DOI:10.1246/cl.1987.177

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