Vicarious Nucleophilic Substitution of Hydrogen versus Bis - Annulation in the Reaction of Chloromethyl Aryl Sulfone Carbanion with Electrophilic Arenes

DOI: 10.1246/cl.1987.61

Source and publish data:

Chemistry Letters p. 61 - 64 (1987)

Update date:2022-08-03

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Authors:

Makosza, Mieczyslaw

Glinka, Tomasz

Ostrowski, Stanislaw

Rykowski, Andrzej

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Article abstract of DOI:10.1246/cl.1987.61

The carbanion of chloromethyl aryl sulfone reacts with 1-Cyanonaphthalene to form a bis-annulated product whereas with 1-nitronaphthalene vicarious nucleophilic substitution of hydrogen takes place.This result and the bis-annulation of quinoxalines and na

Full text of DOI:10.1246/cl.1987.61

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